Frosted anodized aluminum profiles 6xxx series alloys, mainly 6060 and 6063 (AD31), attracts many consumers. It gives a very nice look, in many ways to hide such extrusion defects such as "traces of the die" and has good repeatability from batch to batch.
Alkaline pickling of aluminum
Usually, alkaline degreasing and alkaline etching are used to prepare the surface of aluminum before anodizing - a chemical reaction of aluminum with alkali, usually – с едким натром (NaOH). Thus there is a cleaning of the surface and for bleeding the surface layer in order to increase surface haze and removal or smoothing of visible defects molded surface, such as "traces of the matrix". at aluminum anodizing its surface layer is converted into oxide coating semitransparent. The entire surface topography, which was formed by alkali etching, saved.
E6 alkaline pickling of aluminum
The present matte alkaline etching aluminum profiles obtained in the not conventional alkaline baths containing alkali 30-40 g / l and aluminum to 40 g / l, а в так называемых «вечных» или «долгоживущих» ваннах с повышенным содержанием щелочи (50-80 г/л) и большим содержанием алюминия (120-180 г/л). These baths are called, respectively, bath tub, E0 and E6 on the name of surface preparation mode before anodizing, which are set out in the German standard DIN 17611. The bath is usually handled E0 profiles 2-10 minutes at 40-50 oC, bath and E6 – 10-20 minutes at 60-70 oC.
Average bleeding in the bath is E6 70-100 g / m2. After the alkali etching E6 aluminum surface receives special topography, which intensively disperses most of the incident light, which gives it a matte appearance and ability to mask minor surface defects.
Iron in aluminum
It has long been known, that aluminum alloys 6xxx series with a high content of iron to get a good matte finish is much easier. This is due to the fact, that with increasing iron content increases etch pit density of not only the grain boundary, but within the grains. Этому способствует повышенное количество интерметаллидных частиц Al-Fe(Mn)-Si. These iron particles act as cathodes in aluminum dissolution reaction when an alkaline etching. The "pure" alloy, with a minimum iron, We occur common bleed aluminum matrix without the formation of deep etching pits, and that then provides brilliant, glossy anodized surface. With increasing iron content in the alloy thickness bleed, which is necessary for obtaining a matt surface, decreases.
Copper and zinc in aluminum
Moreover, to achieve a good matte surface of the copper content in the aluminum alloy should be kept to a minimum - to 0,03 %. Elevated levels of copper in the alloy increases the gloss anodized surface. That is why alloys 6463 and 6463A, which is used to produce brilliant, reflective anodizing, the copper content increased - up 0,25 %, iron and low - no more than 0,15 %.
Effect technology on "matteness" of aluminum surface
The manufacturing process of aluminum profiles also has an impact on the matteness of the surface. Полностью гомогенизированная микроструктура слитка для прессования (столба) способствует образованию матовой поверхности. Good training on the press also has a positive effect on the matte surface profiles. The best combination of opacity and mechanical properties gives the typical state T6 - hardening and artificial aging at 185 ° C within 5 hours. Underaging aluminum alloys, including T4 state, It promotes greater brilliance anodized surface. Сильное перестаривание (состояние Т7) – увеличение температуры и/или длительности старения – может дать увеличение матовости поверхности, but at the expense of a significant reduction in the mechanical properties of the profiles.